Aromatics Recovery Process by GTC Technology

GT-BTX is an aromatics recovery technology that uses extractive distillation to remove benzene, toluene, and xylene (BTX) from refinery or petrochemical aromatics streams such as catalytic reformate or pyrolysis gasoline. With lower capital and operating costs, simplicity of operation, and range of feedstock and solvent performance, extractive distillation is superior to conventional liquid-liquid extraction processes. Flexibility of design allows use for grassroots aromatics recovery units, debottlenecking or expansion of conventional extraction systems.

Hydrocarbon feed is preheated with hot circulating solvent and fed at a midpoint into the extractive distillation column (EDC). Lean solvent is fed at an upper point to selectively extract the aromatics into the column bottoms in a vapor/liquid distillation operation. The nonaromatic hydrocarbons exit the top of the column and pass through a condenser. A portion of the overhead stream is returned to the top of the column as reflux to wash out any entrained solvent. The balance of the overhead stream is raffinate product and does not require further treatment.

Rich solvent from the bottom of the EDC is routed to the solventrecovery column (SRC), where the aromatics are stripped overhead. Stripping steam from a closed-loop water circuit facilitates hydrocarbon stripping. The SRC is operated under a vacuum to reduce the boiling point at the base of the column.

Lean solvent from the bottom of the SRC is passed through heat exchange before returning to the EDC. A small portion of the lean circulating solvent is processed in a solvent regeneration step to remove heavy decomposition products.

The SRC overhead mixed aromatics product is routed to the purification section, where it is fractionated to produce chemical-grade benzene, toluene and xylenes.

Process advantages:
• Lower capital cost compared to conventional liquid-liquid extraction or other extractive distillation systems
• Energy integration options to further reduce operating costs
• Higher product purity and aromatic recovery
• Recovers aromatics from full-range BTX feedstock
• Distillation-based operation provides better control and simplified operation
• Proprietary formulation of commercially available solvent exhibits high selectivity and capacity
• Low solvent circulation rates
• Insignificant fouling due to elimination of liquid-liquid contactors
• Fewer hydrocarbon emission sources for environmental benefits.

Licensor: GTC Technology.

fig 1 13 - Aromatics Recovery Process by GTC Technology


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